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Hydro­gen bonds and C—H⋯O ­interactions in the enol tautomer of 4‐­(phenylsulfonyl)spiro­[cyclo­pentane‐1,9′‐[9H]­fluorene]‐2,3‐dione
Authors:Roger E Gerkin
Abstract:The title compound, 2‐hydroxy‐1‐(phenyl­sulfonyl)­spiro­cyclo­pentene‐4,9′‐9H]­fluoren]‐3‐one, C23H16O4S, crystallized in the centrosymmetric space group P21/n with one mol­ecule as the asymmetric unit. The hydroxyl‐H atom is ordered and participates in a single intramolecular hydrogen bond and in a single intermolecular hydrogen bond, in which the OD—H distance is 0.90 (2), H?OA is 2.34 (3), OD?OA is 2.987 (2) Å and OD—H?OA is 129 (2)°. The intermolecular hydrogen bond forms an Rinline image(12) cyclic dimer about a center of symmetry. There are six leading C—H?O interactions. Taken together, these interactions form a three‐dimensional network. Structural comparisons are made with tetrabenzodi­spiro­4.0.4.3]­tridecatetraene.
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