The exo and endo isomers of [N,N′‐bis­(salicyl­idene)‐1,2‐di­phenyl‐(RS,SR)‐1,2‐ethane­diyl­diamin­ato]­oxo­vanadium(IV)

The title complexes, exo‐ and endo‐[VO(C₂₈H₂₂N₂O₂)], show monomeric structures with a distorted square‐pyramidal coordination. The two phenyl groups on the five‐membered N,N′‐chelate ring are both on the same side as the oxo ligand for the exo isomer and on opposite sides for the endo isomer.