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C—H⃛π interactions in 9‐(n‐do­decylamino­methyl)­anthracene
Authors:M Ramos Silva  A Matos Beja  L Alte da Veiga  J A Paixo  A J F N Sobral  N G C L Rebanda  A M d'A Rocha Gonsalves
Institution:M. Ramos Silva,A. Matos Beja,L. Alte da Veiga,J. A. Paixão,A. J. F. N. Sobral,N. G. C. L. Rebanda,A. M. d'A. Rocha Gonsalves
Abstract:The title compound, C27H37N, which is intended to be included in the structure of a sulfon­amide porphyrin for the preparation of Langmuir–Blodgett films, consists of a do­decyl chain linked to an anthracene mol­ecule through an amino­methyl group. The angle between the least‐squares plane of the anthracene and the do­decyl chain is 11.44 (8)°. The mol­ecules are arranged in zigzag layers head‐to‐head, with the hydro­carbon chains side‐by‐side. The structure is stabilized by C—H?π interactions, the strongest having an H?centroid distance of 2.63 Å.
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