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trans‐Di­chlorotetrakis(4‐methyl­pyridine)­silicon bis­(triiodide) chloro­form solvate
Authors:Karl Hensen  Ralf Mayr‐Stein  Stephan Rühl  Michael Bolte
Abstract:At 173 K, the dication of the title compound, C24H28Cl2N4Si2+·2I3?·CHCl3, is located on a crystallographic fourfold rotation axis. The chloro ligands occupy axial positions and the four 4‐methyl­pyridine ligands lie in the equatorial plane. The almost linear I3? ion is located on a crystallographic mirror plane and displays two significantly different I—I bond lengths. Furthermore, chloro­form mol­ecules, which are disordered about a centre of inversion, fill the remaining gaps in the crystal structure.
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