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Current progresses in two-dimensional MXene-based framework: prospects from superficial synthesis to energy conversion and storage applications
Affiliation:1. School of Chemistry and Chemical Engineering, Northwestern Polytechnical University, Xian, China;2. State Key Laboratory of Environmental Criteria and Risk Assessment, National Engineering Laboratory for Lake Pollution Control and Ecological Restoration, Chinese Research Academy of Environmental Sciences, 10012, Beijing, China;3. Electronic Materials Research Laboratory, School of Electronic Science and Engineering, Xi''an Jiaotong University, Xi''an 710049, Shaanxi, China;4. School of Energy and Power Engineering, Shandong University, Jinan 250061, China;5. School of Environmental Science and Engineering, Tianjin University, Tianjin, 300354, People''s Republic of China;6. Institute of Chemical Sciences, Bahaudin Zakariya University, Multan, Pakistan;7. Department of Ocean Science and Engineering, Southern University of Science and Technology, Shenzhen, China;8. Department of Chemical Engineering, Universitat Rovira I Virgili, 43007, Tarragona, Spain;9. Nanotechnology Laboratory, Department of Chemistry, GLA, University, Mathura, Uttar Pradesh, 281406, India;10. Multiscale Computational Materials Facility, Key Laboratory of Eco-Materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350100, China;11. Research Center for Advanced Materials Science (RCAMS), King Khalid University, P.O. Box 9004, Abha, 61413, Saudi Arabia;12. Department of Chemistry, College of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia;13. Department of Physics, Faculty of Science, King Khalid University, P.O. Box 9004, Abha 61413, Saudi Arabia;14. Department of Physics, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia;15. Lithography in Devices Fabirication Research Group, Deanship of Scientific Research, King Abdulaziz University, Jeddah 21589, Saudi Arabia;p. College of Chemistry and Life Sciences, Zhejiang Normal University, Jinhua 321004, Zhejiang PR, China;q. College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, 321004, China
Abstract:MXenes are regarded as a type of two-dimensional (2D) inorganic material, mainly comprising a number of transition metal carbides, nitrides, or carbonitrides atomic planes. Nevertheless, the scientific community is continuously interested in exploring and structuring the engineered-based multifunctional material for numerous applications. The MXenes-based materials in this context, have emerged as highly active compounds owing to their superior surface area, substantial interlayer spacing, highly reactive surface-active sites and surface functional group, even though, recent studies have shown significant scientific and theoretical progress related to enormous prospects in MXenes, chemical nature, robust electrochemistry and high hydrophilicity of MXenes. The role of MXenes in all kinds of strategies is still in an upgrading phase for their further improvement, and is not sufficiently summarized in the literature now. To begin with this, herein, present review article is intended to critically discuss the diversity of MXenes with respect to different composition, formulation, plasmonic, complexation, and numerous geometric and morphological aspects, along with novel construction strategies to improve their surface characteristics in all aforesaid multidimensional applications. Following that, in terms of broadening the application, this review article is envisaged to endorse the use of MXenes and their hybrid configuration in a series of emerging environmental decontamination via adsorption, photodegradation, photocatalytic fuel production via hydrogen evolution, CO2 reduction, electrocatalytic sensing, along with membrane distillation and energy storage. In addition, comprehensive information about existing obstacles and future perspectives have been addressed. Finally, an overview is succinctly summarized and discussed regarding the emerging prospects of MXenes for their potential uses in numerous research fields. At the end, it is anticipated that this review article will pave the way for the effective use of MXenes in different fields of environmental remediation, energy conversion, storage and biomedical applications as an innovative, reliable, and multifunctional material.
Keywords:2D MXenes  Synthesis strategies  Different properties  Morphological aspects  Distinctive composition  Potential applications
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