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Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex
Authors:Legault Claude Y  Kendall Christopher  Charette André B
Affiliation:Département de Chimie, Université de Montréal, P.O. Box 6128, Station Downtown, Montréal, QC, Canada H3C 3J7.
Abstract:The efficient synthesis of aN-benzoyliminoimidazolium ylide provides access to a new type of N-hetereocyclic anionic carbene, from which air stable Ag(I) and Cu(II) complexes and a catalytically active Rh(I) complex were formed.
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