DSC studies of aromatic hydrocarbon picrates |
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Authors: | PG Farrell F Shahidi F Casellato C Vecchi A Girelli |
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Institution: | Department of Chemistry, McGill University, Montreal H3A 2K6 Canada;Stazione sperimentale per i Combustibili, 20097 San Donato Milanese, Milan Italy |
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Abstract: | Melting temperatures, enthalpies and entropies of fusion of a number of crystalline, charge-transfer complexes of aromatic hydrocarbons with 2,4,6-trinitrophenol (picric acid) have been measured, together with the corresponding data for some aromatic hydrocarbons themselves and for picric acid. The data suggest that for this, and for other nitro-aromatic acceptor molecules, enthalpies of fusion of charge-transfer complexes reflect the complexing ability of the electron acceptor, although the contribution of the charge-transfer interaction to the measured enthalpy is small. |
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