Enthalphy of mixing of bromobenzene with n-alkanes,with cyclohexane,and with benzene |
| |
| Authors: | Emmerich Wilhelm A. Inglese J.-P.E. Grolier H.V. Kehiaian |
| |
| Affiliation: | Centre de Recherches de Microcalorimétrie et de Thermochimie du C.N.R.S., Section de Thermodynamique des Alliages et des Mélanges Moléculaires, 26 Rue du 141e R.I.A., F-13003 Marseille France |
| |
| Abstract: | A dynamic flow microcalorimeter of the Picker design was used to measure enthalpies of mixing at 298.15 K and atmospheric pressure of the six binary systems bromobenzene + n-hexane, + n-heptane, + n-nonane, + n-tetradecane, + cyclohexane, and + benzene. Within the homologous series of n-alkane systems, the interaction parameter, h12, calculated from rigid-lattice group contribution theory, decreases weakly with increasing chain length of the alkane. This behavior is quite analogous to that observed with chloro-derivatives of benzene + n-alkane. |
| |
| Keywords: | To whom correspondence should be addressed. |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
