Etudes calorimetriques en milieu solvant organique. V. Enthalpies de dissolution de l'alanate de sodium,NaAlH4, dans le tetrahydrofuranne |
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| Authors: | P Claudy B Bonnetot G Chanixe JM Letoffe |
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| Institution: | Laboratoire de Thermochimie Minérale associé au C.N.R.S. No. 116, I.N.S.A., 20. avenue Albert Einstein, 69621 Villeurbanne Cedex France |
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| Abstract: | The enthalpies of dissolution of sodium tetrahydridoaluminate NaAlH4 in THF have been determined for different concentrations. The enthalpies of dissolution and dilution are exothermic from 1 to 7 · 10?3 M. The enthalpy of dissolution at infinite dilution has been calculated: ΔH∝diss = ?6.38 kcal mole?1. |
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