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针尖增强拉曼光谱:技术、应用和发展
引用本文:任斌,王喜. 针尖增强拉曼光谱:技术、应用和发展[J]. 光散射学报, 2006, 18(4): 288-296
作者姓名:任斌  王喜
作者单位:厦门大学化学化工学院,固体表面物理化学国家重点实验室,化学系,厦门,361005
基金项目:国家自然科学基金(20473067,90206039,20673086),教育部博士点基金(20040384010),新世纪优秀人才计划(NCET-05-0564),霍英东基金(101015)项目资助
摘    要:本文从提高表面拉曼光谱检测灵敏度和空间分辨率两个方面的发展叙述了针尖增强拉曼光谱的原理、方法、特点及最新进展。利用单晶电极上单分子层吸附物种的TERS研究和单壁碳纳米管的TERS成像例证了TERS所具有的高检测灵敏度和高空间分辨率。介绍了TERS理论的最新研究进展,并对TERS的应用前景做了预测。

关 键 词:针尖增强拉曼光谱  表面增强拉曼光谱  空间分辨率  灵敏度  纳米颗粒  单晶
文章编号:1004-5929(2006)04-0288-08
收稿时间:2005-07-01
修稿时间:2005-07-01

Tip-enhanced Raman Spectroscopy——Technique,Applications and Perspectives
REN Bin,WANG Xi. Tip-enhanced Raman Spectroscopy——Technique,Applications and Perspectives[J]. Chinese Journal of Light Scattering, 2006, 18(4): 288-296
Authors:REN Bin  WANG Xi
Affiliation:State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiarnen University, Xiarnen 361005, China
Abstract:The principle, technique, the features and the most recent development of Tip-Enhanced Raman Spectroscopy (TERS) were introduced from the aspects of how to improve the detection sensitivity and the spatial resolution of Raman spectroscopy. The high sensitivity of TERS was demonstrated using the molecular adsorption on single crystal surfaces and the high spatial resolution was demonstrated by imaging single-wall carbon nanotubes. The present status of the theoretical aspect of TERS was also introduced. Finally the perspective of TERS was given.
Keywords:Tip-Enhanced Raman Spectroscopy  Surface-Enhanced Raman Spectroscopy  spatial resolution  sensitivity  nanoparticles  single crystal surface
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