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Paramagnetic surface active ionic liquids: synthesis,properties, and applications

Authors:	A Kulshrestha PS Gehlot A Kumar

Institution:	1. Salt and Marine Chemicals Division, CSIR-Central Salt and Marine Chemicals Research Institute (CSIR-CSMCRI), Gijubhai Badheka Marg, Bhavnagar 364002, Gujarat, India;2. Academy of Scientific and Innovative Research, Ghaziabad 201002, India;3. Department of Chemistry, Government Science College Pardi, Valsad 396125, Gujarat, India

Abstract:	Paramagnetic surface active ionic liquids (PMSAILs) classify task-specific ionic liquids with magnetic properties by incorporating metal into the cationic or anionic part of the ionic liquid. Paramagnetic ionic liquids had long-chain either in cations or anions and showed excellent surface activity and magnetic properties without any need for the magnetic nanoparticles. These PMSAILs have inherent unique ionic liquid properties and self-assembled into various nano-aggregates such as micelles, vesicles, rod-like micelles, and etc., by modification in the structure of cations or anions. PMSAILs provide stimuli-responsive properties, which is one of the essential aspects of targeted applications. The appropriate functional tunability of anions and cations in PMSAILs leads to various multifaceted chemical and biological applications. A new emerging trend in PMSAIL research is hybridization with flexible materials. This review will mainly deal with the synthesis, characterization, and brief history of PMSAILs and their potential advantages in the various applications in micellar catalysis, purification and separation of biomolecules, compaction and decompaction of DNA, drug delivery, and other biomedical applications.

Keywords:	Micellar catalysis Drug delivery Aggregation behavior MRI contrasting agent DNA compatible ILs"} {"#name":"keyword" "$":{"id":"kwrd0040"} "$$":[{"#name":"text" "_":"ionic liquids SAILs"} {"#name":"keyword" "$":{"id":"kwrd0050"} "$$":[{"#name":"text" "_":"surface active ionic liquids MILs"} {"#name":"keyword" "$":{"id":"kwrd0060"} "$$":[{"#name":"text" "_":"magnetic ionic liquids PMSAIL"} {"#name":"keyword" "$":{"id":"kwrd0070"} "$$":[{"#name":"text" "_":"paramagnetic surface active ionic liquids MSAIL"} {"#name":"keyword" "$":{"id":"kwrd0080"} "$$":[{"#name":"text" "_":"metal based surface active ionic liquids DNA"} {"#name":"keyword" "$":{"id":"kwrd0090"} "$$":[{"#name":"text" "_":"deoxyribonucleic acid MRI"} {"#name":"keyword" "$":{"id":"kwrd0100"} "$$":[{"#name":"text" "_":"magnetic resonance imaging PCR"} {"#name":"keyword" "$":{"id":"kwrd0110"} "$$":[{"#name":"text" "_":"polymerase chain reaction RTILs"} {"#name":"keyword" "$":{"id":"kwrd0120"} "$$":[{"#name":"text" "_":"room temperature ionic liquids MALDI"} {"#name":"keyword" "$":{"id":"kwrd0130"} "$$":[{"#name":"text" "_":"matrix-assisted laser desorption/ionization PILs"} {"#name":"keyword" "$":{"id":"kwrd0140"} "$$":[{"#name":"text" "_":"poly ionic liquids SILMs"} {"#name":"keyword" "$":{"id":"kwrd0150"} "$$":[{"#name":"text" "_":"supported IL membranes TSILs"} {"#name":"keyword" "$":{"id":"kwrd0160"} "$$":[{"#name":"text" "_":"task-specific ILs 1-butyl-3-methyl imidazolium tetrachloroferrate(III) 1-butyl-3-methyl imidazolium hexafluorophosphate tetrachloroferrate(III) bromotrichloroferrate(III) tetrachlorocobaltate(II) tetrachloromanganate(II) tetrachlorocuprate(II) hexachlorogadolinite(III) benzyltrioctylammonium bromotrichloroferrate(III) 1-dodecyl-3-methylimidazolium bromotrichloroferrate(III) 1-dodecylpyridinium bromotrichloroferrate(III) 1-dodecyl isoquinolinium bromotrichloroferrate(III) tetradecyltrihexyl phosphonium tetrachloroferrate(III) DTAB"} {"#name":"keyword" "$":{"id":"kwrd0300"} "$$":[{"#name":"text" "_":"dodecyltrimethylammonium bromide CD"} {"#name":"keyword" "$":{"id":"kwrd0310"} "$$":[{"#name":"text" "_":"circular dichroism ITC"} {"#name":"keyword" "$":{"id":"kwrd0320"} "$$":[{"#name":"text" "_":"isothermal titration calorimeter DLS"} {"#name":"keyword" "$":{"id":"kwrd0330"} "$$":[{"#name":"text" "_":"dynamic light scattering DSC"} {"#name":"keyword" "$":{"id":"kwrd0340"} "$$":[{"#name":"text" "_":"differential scanning calorimeter TGA"} {"#name":"keyword" "$":{"id":"kwrd0350"} "$$":[{"#name":"text" "_":"thermogravimetric analysis LCMS"} {"#name":"keyword" "$":{"id":"kwrd0360"} "$$":[{"#name":"text" "_":"liquid chromatography-mass spectroscopy
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