Recent advancement in inorganic-organic electron transport layers in perovskite solar cell: current status and future outlook |
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Authors: | A Raj M Kumar A Anshul |
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Institution: | 1. CSIR-National Environmental Engineering Research Institute (NEERI), Nagpur, 440020, India;2. Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, 201002, India;3. Experimental Research Laboratory, Department of Physics, ARSD College, University of Delhi, New Delhi, 110021, India |
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Abstract: | Organic-inorganic lead halide perovskite solar cells have captured significant attention in recent years due to low processing costs and unprecedented development in power conversion efficiency (PCE). It has appeared from 2009 with PCE of 3.8% to being claimed more than 25.2% PCE in a very short span of time, showing their future prospective toward the fabrication of less expensive and stable solar cells. The incredible advancement in this technology encourages at one end, whereas several hurdles restricting its complete utilization for commercial purposes at another end. Although the selection of perovskite structure is limited with planar and mesoporous electron transport layers (ETLs), but identification of appropriate ETLs necessitates excellent effort to improve the surface morphology of absorber and obtain enhanced PCE with higher stability. In the present review, we have investigated various inorganic-organic ETLs with different device configurations of PSCs, primarily focusing on crystallization and morphology control techniques of ETL thin films. Numerous strategies such as surface functionalization, doping, and addition of interfacial layer are adopted for ETLs, and their effect on device efficiency, performance, and hysteresis is also discussed in detail. Additionally, designs of PSCs with different device configurations are discussed as well, providing future guidelines for significant progress in PSCs structure with different ETLs. |
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Keywords: | Low-temperature processing Hysteresis effects Doping Fullerene Organic ETLs |
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