Layered V-MOF nanorods for rechargeable aqueous zinc-ion batteries |
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Authors: | Yue Ru Shasha Zheng Huaiguo Xue Huan Pang |
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Institution: | School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, PR China |
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Abstract: | Metal–organic frameworks (MOFs) have attracted great attention owing to their controllable morphologies, adjustable aperture, and large specific surface areas. Here, a typical V-MOF (MIL-47) product is successfully synthesized via a one-step hydrothermal method, which is explored to have a one-dimensional layered nanorod-like framework. From a microcosmic point of view, such a V-MOF product is equipped with a rhomboid structure with a large number of empty channels, which is beneficial for guest ions freely inserting in and extracting from the structure. Hence, the V-MOF product is utilized as the cathode material for the aqueous MOF-Zn battery, which exhibits a high initial specific capacity of 320 mA h/g at 0.1 A/g, and a desirable rate capability and cycling performance. |
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Keywords: | Metal–organic frameworks One-dimensional layered nanorods Rhomboid structure Aqueous MOF-Zn batteries |
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