The role of hydrogen atoms in CIDNP effects in the reaction of diisobutylaluminum hydride with CCl4 |
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| Authors: | R. A. Sadykov I. Kh. Teregulov |
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| Affiliation: | (1) Institute of Petrochemistry and Catalysis, Bashkortostan Republic Academy of Sciences and Ufa Research Center of the Russian Academy of Sciences, 141 prosp. Oktyabrya, 450075 Ufa, Russian Federation;(2) Institute of Organic Chemistry, Ufa Research Center of the Russian Academy of Sciences, 71 prosp. Oktyabrya, 450054 Ufa, Russian Federation |
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| Abstract: | Integral polarization of chloroform, methylene dichloride, and pentachloroethane was observed in the1H NMR spectra during the exothermal reaction of a 1M solution of Bu2 i in 1,4-dioxane with CCI4. CIDNP was shown to appear in the diffusion radical pair of the hydrogen atom and trichloromethyl radical. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 10, pp. 2097–2099, October, 1998. |
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| Keywords: | CIDNP hydrogen atom trichloromethyl radical radical reaction diisobutylaluminum hydride carbon tetrachloride |
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