Studies on the synthesis of myriaporones: stereoselective synthesis of the C5-C13 fragment starting from D-glucose via regioselective reductive opening of methoxybenzylidene acetal |
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| Authors: | Zheng B Z Yamauchi M Dei H Yonemitsu O |
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| Institution: | Department of Chemistry, Okayama University of Science, Japan. |
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| Abstract: | A stereoselective synthesis is described of the C5-C13 fragment (4) of myriaporone 4 (1) starting from D-glucose by a coupling of the C5-C9 aldehyde (5), prepared using a regioselective reductive ring-opening of methoxybenzylidene acetal, with the C10-C13 iodoolefin (6). |
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