A porphyrin nanochannel: formation of cationic channels by a protonated saddle-distorted porphyrin and its inclusion behavior |
| |
Authors: | Harada Ryosuke Kojima Takahiko |
| |
Institution: | Department of Chemistry, Faculty of Sciences, Kyushu University, Hakozaki, Higashi-Ku, Fukuoka 812-8581, Japan. |
| |
Abstract: | A highly saddle-distorted dodecaphenylporphyrin dication (H4DPP2+) was revealed by X-ray crystallography to form positively charged porphyrin nanochannels which were 1 nm in diameter; chloride anion and redox-active hydroquinone could be incorporated in the channels. |
| |
Keywords: | |
本文献已被 PubMed 等数据库收录! |
|