Chiral recognition by molecularly imprinted polymers in aqueous media |
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| Authors: | O. Ramström L. Ye P. -E. Gustavsson |
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| Affiliation: | (1) Pure and Applied Biochemistry, Center for Chemistry and Chemical Engineering, Lund University, P.O. Box 124, 221 00 Lund, Sweden |
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| Abstract: | Summary Molecularly imprinted polymers were prepared using 2-vinylpyridine and/or methacrylic acid as functional monomers in a self-assembly imprinting protocol. The resulting polymers were analyzed in aqueous media, and the effects from the pH of the mobile phase and the degree of added organic solvent were investigated. The results are indicative of the importance of ionic bonds in conjunction with hydrophobic interactions in the formation of the complexes between the analyte and the polymers. |
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| Keywords: | Column liquid chromatography Molecular imprinting Molecular recognition Chiral recognition |
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