Photochemical transformations of cyclic acetal radical cations in Freon matrices at 77 K |
| |
| Authors: | M. Ya. Mel’nikov E. A. Belokon’ V. N. Belevskii A. D. Kalugina O. L. Mel’nikova V. I. Pergushov M. P. Egorov |
| |
| Affiliation: | (1) Department of Chemical Kinetics, Moscow, Russia;(2) Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninskii pr. 47, Moscow, 119991, Russia |
| |
| Abstract: | The efficiency of photochemical reactions of radical cations of cyclic acetals (1,3-dioxolane, 1,3-dioxane) is measured in different Freon matrices at 77 K and the influence of the latter on the reaction path is discovered. The possible nature of the paramagnetic complexes that form in photochemical reactions of cyclic acetal radical cations in Freon-11 is suggested. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
