Giant molecular spoked wheels in giant voids: two-dimensional molecular self-assembly goes big |
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| Authors: | Tahara Kazukuni Lei Shenbin Mössinger Dennis Kozuma Hiroyoshi Inukai Koji Van der Auweraer Mark De Schryver Frans C Höger Sigurd Tobe Yoshito De Feyter Steven |
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| Institution: | Division of Frontier Materials Science, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka, Japan. tobe@chem.es.osaka-u.ac.jp |
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| Abstract: | We present here the formation of giant pores in surface-confined molecular networks of a triangular-shaped dehydrobenzo-12]annulene derivative: the diameter of the pores reaches over 7 nm and the giant pores are used as templates to accommodate a giant molecular spoked wheel, which allows us to observe rotational and adsorption-desorption dynamics of single guest molecules. |
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