Excess enthalpies and apparent molar volumes of some N-methyl substituted amino acids in aqueous solutions |
| |
Authors: | J F Reading P A Carlisle G R Hedwig I D Watson |
| |
Institution: | (1) Department of Chemistry and Biochemistry, Massey University, Palmerston North, New Zealand |
| |
Abstract: | The excess enthalpies and limiting partial molar volumes at 25°C for aqueous solutions of N-methyl glycine, N-methyl alanine, and N-methyl serine are reported and compared with the same properties for the parent amino acids. For each N-methyl derivative the enthalpic contribution to the pairwise interaction is less favorable than that for the parent amino acid. The contribution of the N-methyl substituent to V
2
0
is similar for each amino acid, and is about 2 cm3-mol–1 greater than for a methyl substituent on the -carbon. These observations have been rationalized in terms of the likely solute-solvent interactions. In addition a rigid particle model is used with the volume data to examine solute-solvent interactions. |
| |
Keywords: | Enthalpies of dilution density partial molar volume N-methyl amino acid aqueous solution |
本文献已被 SpringerLink 等数据库收录! |