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Incorporation of Dyes into Polystyrene-block-poly(4-vinylpyridine) Nanotemplates
Authors:Radim K?enek  V?ra Cimrová  Manfred Stamm
Institution:1. Department of Nanostructured Materials, Leibniz Institute of Polymer Research Dresden, Hohe Str. 6, D-01069 Dresden, Germany;2. Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06 Prague 6, Czech Republic
Abstract:Summary: The present study provides some basic concepts of functionalization of diblock copolymer (BC) nanotemplates for optical applications. It is focused on the polystyrene-block-poly(4-vinylpyridine) (PS-b-P4VP) building medium which is suitable for hydrogen bonding, undergoes phase segregation, and is well-accessible. Two techniques are described and demonstrated on several dye complexes with PS-b-P4VP. Relation between optical properties and thin film structure is tentatively studied in dependence on solvent effects in thin films.
Keywords:diblock copolymers  dyes/pigments  functionalization of polymers  templates
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