EPR determination of the rate constants of detachment of hydrogen from triethylsilane by metal carbonyl radicals |
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Authors: | R G Gasanov S Kh Dotdaev |
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Institution: | (1) A. N. Nesraeyanov Institute of Organoelemental Compounds, Academy of Sciences of the USSR, Moscow |
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Abstract: | Conclusions The rate constants of detachment of hydrogen from triethylsilane by radicals of rhenium and manganese pentacarbonyls, tungsten cyclopentadienyltricarbonyl, and iron eyclopentadienyldicarbonyl were determined, and the order of the reactivity of the metal carbonyls was hypothesized.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1981–1987, September, 1986. |
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