Analysis of the Gor'skii-Bragg-Williams model |
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Authors: | Yu I Paskal' L I Valovskaya |
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Institution: | (1) V. D. Kuznetsov Siberian Physicotechnical Institute, Tomsk State University, USSR |
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Abstract: | The concentration dependence predicted for the degree of long-range order at constant temperature by the Gor'skii-Bragg-Williams model is analyzed. It is shown why the AB3 superstructure cannot form during equilibrium ordering of a solution with cB < 0.5. It is shown that this model predicts a (usually metastable) equilibrium of two ordered phases (based on the A3B and AB3 superstructures) in a certain concentration range.Translated from Izvestiya VUZ. Fizika, No. 7, pp. 43–47, July, 1970. |
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