Crystal structure of bis(iso-maleonitril-edithiolate)nickel(II) benzylpiperidinium |
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| Authors: | Y -L Hu L -B Liang J -F Liu W -Q Chen J -R Zhou X -P Liu L -M Yang C -L Ni |
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| Institution: | 1. Department of Applied Chemistry, College of Science, Institute of Biomaterials, South China Agricultural University, 510642, Guangzhou, P. R. China
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| Abstract: | Bis(iso-maleonitriledithiolate)nickel(II) benzylpiperidinium, BzPid]2Ni(i-mnt)2] (1) is prepared and characterized by elemental analyses, UV, IR, molar conductivity, and single crystal X-ray diffraction. It is found that 1 crystallizes in the monoclinic space group P21/n with a = 9.551(1) Å, b = 16.520(2) Å, c = 11.004(1) Å, β = 96.60(1)°, V = 1724.6(3) Å3, Z = 2. Consolidate the stacking of the molecules The electrostatic interaction between Ni(i-mnt)2]2? anions and BzPid]+ cations consolidates the stacking of the molecules. |
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