Synthesis and ESR spectra of [4,6-di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzosemiquinonato]thallium(i)

[4,6-Di-tert-butyl-N-(2,6-diisopropylphenyl)-o-iminobenzosemiquinonato]thallium(i) was synthesized and characterized by IR and ESR spectroscopy. The hyperfine coupling constants with ^203/205Tl nuclei were found to depend strongly on the nature (solvating ability) of solvents. At 298 K, the HFC constant a_Tl changes from 3.09 mT in n-hexane up to 19.70 mT in tetramethylethylenediamine. The coordination number of solvation was found to be 1 for DMF—benzene and pyridine—hexane systems. The thermodynamic characteristics of solvation in the pyridine—hexane system were determined.