2-[(4'-N,N-二甲胺基)苯乙烯基]-5-二米基硼-噻吩的合成-结构与光物理性质 |
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引用本文: | 刘志强,方奇,王东,薛刚,曹笃霞,于文涛,夏光明.2-[(4'-N,N-二甲胺基)苯乙烯基]-5-二米基硼-噻吩的合成-结构与光物理性质[J].化学学报,2003,61(9):1449-1454. |
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作者姓名: | 刘志强 方奇 王东 薛刚 曹笃霞 于文涛 夏光明 |
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作者单位: | 山东大学晶体材料国家重点实验室,济南250100 |
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基金项目: | 国家自然科学基金 (No.2 0 1 72 0 34),高等学校骨干教师资助计划,国家重点基础研究发展规划 (973计划 )资助项目 |
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摘 要: | 合成了以含硼(III)基团为电子受体,以二甲胺基为电子给体,以苯乙烯基 噻吩为共轭桥的新化合物2-(4'-N,N-二甲胺基)苯乙烯基]-5-二米基硼-噻吩 trans-2-(4'-N, N-dimethylamino) styryl]-5-dimesitylboryl-thiophene(简 写为DMASBT,5)。X射线衍射方法测定其单晶结构表明,硼原子与π共轭桥之间的 硼碳键相对于其它的硼碳键明显缩短,硼与π共轭桥之间存在除了σ键之外的p-π 共轭作用。研究了它在不同溶剂中的光物理性质,发现它具有突出的溶致变色效应 。在极性较大的溶剂中,有较高的荧光量子产率和较长的荧光寿命。激光实验发现 ,DMASBT在近红外波段(750~850 nm)有较强的非线性吸收,用波长为800 nm的 红色飞秒激光激发时,DMASBT在四氢呋喃中发现波长为559 nm的强的绿色上转换荧 光。
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关 键 词: | 硼烷 上转换荧光 噻吩 P X射线衍射分析 量子产量 |
修稿时间: | 2003年12月27 |
Synthesis, Structure and Photo-Physical Property of trans-2-[(4'-N, N-dimethylamino) styryl]-5-dimesitylborylthiophene |
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Institution: | State Key Laboratory of Crystal Materials, Shangdong University |
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Abstract: | A new organic compound, trans-2-( A'-N, iV-dimethylamino ) styryl ] -5-dimesitylborylthiophene (abbreviated as DMASBT, 5) with dimesitylboryl, dimethylamino and styryl-thiophene as electron acceptor, electron donor and conjugate bridge respectively, was synthesized. Its crystal structure determined by X-ray diffraction method indicates that the B-C bond between B atom and it bridge is obviously shorter than those of between B atom and mesityl groups. This remarkably strengthened B-C bonding can be regarded as an evidence of additional p-7t conjugation between the B atom and n bridge. The photo-physical properties of 5 in various solvents were studied in details. With the increasing of the polarity of solvents, the emission band of 5 will be remarkably red-shifted, its quantum yield will be increased and the lifetime will be lengthened. 5 Shows strong nonlinear absorption in the NIR band (750 ~ 850 nm) in the laser experiments in THF solution. Especially when it was irradiated by a femto-second laser at 800 nm, a strong up-converted green fluorescence in THF was observed. |
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Keywords: | organoboron compound DMASBT up-converted fluosescence |
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