Facile synthesis of a flexible tethered porphyrin dimer that preferentially complexes fullerene C70 |
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Authors: | Jurow Matthew Farley Christopher Pabon Cesar Hageman Brian Dolor Aaron Drain Charles Michael |
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Affiliation: | Hunter College and Graduate Center of the City University of New York, 695 Park Avenue, New York, New York 10065, USA. |
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Abstract: | A simple, high yield, two-step synthesis yields a porphyrin dimer linked by a flexible dithiol tether that preferentially binds fullerene C(70) over C(60) in toluene solution. The complex forms stable aggregates when cast on glass. |
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