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Facile synthesis of a flexible tethered porphyrin dimer that preferentially complexes fullerene C70
Authors:Jurow Matthew  Farley Christopher  Pabon Cesar  Hageman Brian  Dolor Aaron  Drain Charles Michael
Affiliation:Hunter College and Graduate Center of the City University of New York, 695 Park Avenue, New York, New York 10065, USA.
Abstract:A simple, high yield, two-step synthesis yields a porphyrin dimer linked by a flexible dithiol tether that preferentially binds fullerene C(70) over C(60) in toluene solution. The complex forms stable aggregates when cast on glass.
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