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Preparation and reactivity of O2-sulfonated diazeniumdiolates
Authors:D'Sa Raechelle A  Wang Yuhong  Ruane Patrick H  Showalter Brett M  Saavedra Joseph E  Davies Keith M  Citro Michael L  Booth Melissa N  Keefer Larry K  Toscano John P
Institution:Department of Chemistry, Johns Hopkins University, 3400 North Charles Street, Baltimore, Maryland 21218, USA.
Abstract:We report the facile preparation of O2-sulfonated diazeniumdiolates and mechanistic investigation of their reactions with representative nucleophiles. This new class of compounds extends the range of O2-substituted diazeniumdiolates available for potential applications in research and medicine.
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