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Efficient synthesis of isoindoles using supercritical carbon dioxide |
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| Authors: | Satoshi Ito Masayuki Akaki Yasutaka Shinozaki Yuuki Iwabe Masaru Furuya Marina Tobata Makoto Roppongi Takafumi Sato Naotsugu Itoh Toru Oba |
| Affiliation: | 1. Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University, 7-1-2 Yoto, Utsunomiya, Tochigi 321-8585, Japan;2. Collaboration Center for Research and Development of Utsunomiya University, 7-1-2 Yoto, Utsunomiya, Tochigi 321-8585, Japan |
| Abstract: | Bicyclopyrroles were efficiently converted to the corresponding isoindoles by a retro Diels-Alder reaction in supercritical carbon dioxide. By adding ethylene gas as an oxygen scavenger, the isoindole yield was further improved. |
| Keywords: | Isoindole Supercritical carbon dioxide Bicyclopyrrole Corresponding author. |
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