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Vanadocene arsenate complexes: evidence of super‐hyperfine coupling with 75As |
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| Authors: | Jan Honzíček Jaromír Vinklárek Pavel Kratochvíl Jan Hrbáč |
| Affiliation: | 1. Department of General and Inorganic Chemistry, Faculty of Chemical Technology, University of Pardubice, 532 10 Pardubice, Czech Republic;2. Department of Physical Chemistry, Faculty of Science, Palacky University, 77146 Olomouc, Czech Republic |
| Abstract: | The reaction of vanadocene dichloride with sodium arsenate gives Cp2V(O2AsO2H). This compound was identified on the basis of the super‐hyperfine coupling observed in the solution EPR spectrum. The effect of substitution was studied on the ring‐substituted and ansa‐bridged compounds. Copyright © 2010 John Wiley & Sons, Ltd. |
| Keywords: | EPR spectroscopy super‐hyperfine coupling bent metallocene vanadocene dichloride |