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Improved approximations for some polymer extension models
Authors:Rafayel?Petrosyan  author-information"  >  author-information__contact u-icon-before"  >  mailto:rafayel.petrosyan@alumni.ethz.ch"   title="  rafayel.petrosyan@alumni.ethz.ch"   itemprop="  email"   data-track="  click"   data-track-action="  Email author"   data-track-label="  "  >Email author
Affiliation:1.Department of Biosystems Science and Engineering,Eidgen?ssische Technische Hochschule (ETH) Zurich,Basel,Switzerland;2.Department of Physics,University of Alberta,Edmonton,Canada
Abstract:We propose approximations for force-extension dependencies for the freely jointed chain (FJC) and worm-like chain (WLC) models as well as for extension-force dependence for the WLC model. Proposed expressions show less than 1 % relative error in the useful range of the corresponding variables. These results can be applied for fitting force-extension curves obtained in molecular force spectroscopy experiments. Particularly, they can be useful for cases where one has geometries of springs in series and/or in parallel where particular combination of expressions should be used for fitting the data. All approximations have been obtained following the same procedure of determining the asymptotes and then reducing the relative error of that expression by adding an appropriate term obtained from fitting its absolute error.
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