Intermolecular Hydrogen Bonding and Structure of 1,1-Diphenylethanol |
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Authors: | B. Yu. Sultanly A. N. Shnulin R. É. Aliev M. N. Maharramov |
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Affiliation: | (1) Baku State University, 23 Z. Khalilov Str., Baku, 370148, Azerbaijan |
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Abstract: | By the method of IR spectroscopy the hydrogen bonds of 1,1-diphenylethanol (DPE) depending on the concentration in the CCl4 solution and temperature have been investigated. It has been found that hydrogen bonds in crystalline DPE form a tetramer, and in a solution with a concentration of 0.5 mole/liter, cyclic dimers are formed which, with increasing concentration, pass into a cyclic tetramer. |
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Keywords: | IR spectrum temperature solution concentration hydrogen bond |
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