Synthesis and biomimetic rearrangement of a chiral diterpene dioxide |
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| Authors: | Thomas Lindel Burchard Franck |
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| Affiliation: | Organisch-Chemisches Institut der Universität, Corrensstraße 40, D-8149 Münster, Germany |
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| Abstract: | As pan of a biomimetic approach towards me marine triterpene teurilene (2), the synthesis of the chiral diepoxide 3 is described. Aiming at the synthesis of the squalene tetraepoxide 1, double Sharpless epoxidation led to the intermediate bisglycidic alcohol 7 being subject to a stereochemical analysis. |
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