Institution: | Dipartimento di Chimica Generale, Università, I-27100 Pavia Italy Dipartimento di Chimica Fisica, Università, I-30123 Venezia Italy Physik-Department, Technische Universität München, D-85747 Garching Germany Dipartimento di Scienze Chimiche, Università, I-62032 Camerino Italy |
Abstract: | Reactions of the trinuclear Au3Rim3] compound (Rim = μ-1-benzylimidazolato-N3,C2] with several reagents capable of oxidative addition have been investigated by 197Au Mössbauer spectroscopy. The reaction products are either AuI carbene mononuclear and binuclear complexes or trinuclear AuIII and mixed-valence compounds. The X-ray crystal structure of the mixed-valence complex AuIIIAuI2Rim3I2] has been determined. Two two-coordinate AuI centres show average Au---C and Au---N distances of 2.02(3) and 2.04(2) Å and average C---Au---N angles of 175.0(1.2)°, whereas the four-coordinate AuIII centre gives Au---C and Au---N 1.96(4) and 1.91(3) Å with the C---Au---N angle 170.5(1.6)°, and Au---I average distances 2.598(3) Å, with an I---Au=I angle 175.8(1)°. The Au---Au intramolecular distances Au(1) Au(2) 3.432(3), Au(1) Au(3) 3.508(3), Au(2) Au(3) 3.464(3) Å] indicate a weak metal-metal interaction. |