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Relaxation properties of weakly coupled classical systems
Authors:Victor Romero-Rochin  Irwin Oppenheim
Institution:(1) Department of Chemistry, Massachusetts Institute of Technology, 02139 Cambridge, Massachusetts
Abstract:The relaxation properties of a small classical system weakly coupled to a large classical system which acts as a heat bath are described using a generalized Fokker-Planck equation. The Fokker-Planck equation is derived in general using a modification of the elimination of fast variables techniques previously described. The specific example in which the small system is a harmonic oscillator linearly coupled to the heat bath is treated in detail and it is demonstrated that there is a dynamic frequency shift as well as a statistical shift of the oscillator frequency.
Keywords:Relaxation  weak coupling  Fokker-Planck equation
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