A High Yielding, One-Pot, Triton-B Catalyzed, Expeditious Synthesis of Carbamate Esters by Four Component Coupling Methodology |
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Authors: | Devdutt Chaturvedi S Ray |
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Institution: | (1) Medicinal & Process Chemistry Division, Central Drug Research Institute, 226001 Lucknow, India |
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Abstract: | Summary. A novel process for the one-step chemoselective conversion of alkyl halides into carbamates as protected amines was developed
using benzyltrimethylammonium hydroxide (Triton-B) in presence of gaseous carbon dioxide. Thus, carbamate esters of different
amines were prepared in very good to excellent yields.
Present address: Institute of Organic and Biomolecular Chemistry, George–August University, 37077, G?ttingen, Germany |
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Keywords: | , Alkyl halides, Dimethylaminopyridine, Triton-B, Carbon dioxide, N-Alkyl/aryl carbamate, |
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