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Photoemission from the valence bands of Ce(1 1 1) on W(1 1 0)
Authors:O. Morimoto  H. Kato  Y. Sakisaka
Affiliation:a Hiroshima Synchrotron Radiation Center, Hiroshima University, 2-313 Kagamiyama, Higashi-Hiroshima 739-0046, Japan
b Faculty of Science and Technology, Hirosaki University, Hirosaki 036-8561, Japan
Abstract:We report a photoelectron spectroscopic study of the valence bands of epitaxial Ce(1 1 1) films grown on W(1 1 0) at room temperature. The evolution of γ → α → γ like phase transition of Ce is observed with increasing Ce coverage and the valence-band structures of γ-like Ce film are determined. The 4f and 5d photoemission cross sections in the photon energy region from 20 eV to 130 eV are presented and discussed. A 5d-like surface state and a 6s band bottom are identified.
Keywords:Cerium   Tungsten   Photoelectron spectroscopy   Valence band
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