1H NMR spectra and electronic structure of 3-arylmethyl-idenephthalide and 3-arylthiomethylidenephthalide derivatives |
| |
Authors: | M Vida V Kell T Liptaj A Perjssy P Hrn
iar M Lcov |
| |
Institution: | M. Vida,V. Kellö,T. Liptaj,A. Perjéssy,P. Hrnčiar,M. Lácová |
| |
Abstract: | The 1H NMR spectra of trans-3-phenylmethylidenephthalide and trans-3-phenylthiomethylidenephthalide derivatives were investigated. After applying a correction for the anisotropy of substituents and/or for changes of ring current in the substituted aromatic ring, linear correlations were obtained between the chemical shifts of protons of the substituted phenyl group and the methine group and s? constants of substituents. The influence of the bridge heteroatom on the transfer of electronic effects of substituents through the molecules under study is discussed. |
| |
Keywords: | |
|
|