Stereoselective Conjugate Additions of Alcohols to a Chiral (E)-Nitroalkene Derived From (R)-2,3-Isopropylidene Glyceraldehyde |
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| Authors: | Qian Cheng Takayuki Oritani Alfred Hassner |
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| Affiliation: | 1. Laboratory of Applied Bioorganic Chemistry, Division of Life Science Graduate School of Agricultural Science, Tohoku University 1--1 Tsutsumidori-Amamaiyamachi , Aoba-ku, Sendai, 981--8555, Japan;2. Department of Chemistry , Bar-Ilan University , Ramat-Gan, 52900, Israel |
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| Abstract: | Addition of functionalized alcohols to a chiral (E)-nitroalkene proceeded with modest to high diastereoselectivities depending on the presence of metal catalysts in low temperature. The results indicated that anti-selectivities were preferred in all cases. |
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