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Stereoselective Cross-Coupling of Baylis–Hillman Acetates with Diphenyl Disulfides and Diselenides Using Palladium Acetate
Authors:P. Surendra Reddy  M. Amarnath Reddy  M. V. Basaveswara Rao
Affiliation:1. Inorganic and Physical Chemistry Division , Indian Institute of Chemical Technology , Hyderabad, India;2. Department of Pharmaceutical Chemistry , Krishna University , Machlipatnam, India
Abstract:An efficient method is described for the stereoselective synthesis of diorganyl chalcogenides from a variety of Baylis–Hillman acetates and diaryl chalcogens using palladium catalyst. This reaction is a convenient new method to produce unsymmetrical sulfides and selenides in good yields.
Keywords:Baylis–Hillman acetates  diaryl chalcogens  stereoselective cross-coupling  thioethers
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