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Cyanosilylation of Prochiral Ketones Catalyzed by Lanthanide Complexes
Authors:Professor Luo Mei  Ma Huai Zhu
Affiliation:1. Hefei University of Technology, Department of Chemical Engineering , Hefei, China luomeihuahua@sohu.com;3. Anhui Normal University , Wu Hu, Anhui, China
Abstract:A new series of silylene‐bridged rare‐earth complexes involving fluorenyl are shown to be the very efficient Lewis acid catalysts, giving some cyano trimethylsilyl ethers of ketones in >99% yields.
Keywords:Cyano trimethylsilyl ethers of ketones  Lewis acid catalysts  silylene‐bridged rare‐earth complexes involving fluorenyl
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