Synthesis of gem-Dihydroperoxides from Ketones and Aldehydes Using Silica Sulfuric Acid as Heterogeneous Reusable Catalyst |
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| Authors: | Davood Azarifar Zohreh Najminejad Kaveh Khosravi |
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| Institution: | 1. Department of Chemistry , University of Bu-Ali Sina , Hamedan , Iran azarifar@basu.ac.ir;3. Department of Chemistry , University of Bu-Ali Sina , Hamedan , Iran |
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| Abstract: | Silica sulfuric acid (SSA) was found to efficiently catalyze the conversion of aldehydes and ketones directly into the corresponding gem-dihydroperoxides (DHPs) on treatment with aqueous 30% H2O2 at room temperature. Mild reaction conditions, good to excellent yields, short reaction times, low environmental impact, and recyclability of the catalyst are the main advantages of this synthetic method. |
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| Keywords: | Aldehydes gem-dihydroperoxides heterogeneous catalyst ketones silica sulfuric acid |
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