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Oxidation of Benzoins to Benzils with Chromium Trioxide Under Viscous Conditions |
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| Authors: | Li-Hong Huang Qiang Wang Yi-Chun Ma Changhe Zhang |
| Institution: | 1. College of Life Sciences , China Jiliang University , Hangzhou , Zhejiang , China;2. Sirnaomics, Inc. , Gaithersburg , Maryland , USA;3. Centre for the Research and Technology of Agro-Environmental and Biological Sciences (CITAB)/Department of Biology and Environment , Universidade de Trás-os-Montes e Alto Douro (UTAD) , Vila Real , Portugal |
| Abstract: | Reaction of chiral allylic cyclic carbonates with Grignards reagent in the presence of NiCl2(dppe) as a catalyst afforded the alkylated (E)-allylic alcohols with high regio- and diastereoselectivity. |
| Keywords: | Benzils benzoins chromium trioxide oxidation viscous conditions |