Synthesis of 1,2-Disubstituted Ferrocene Containing a Heteroaryl Group |
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| Authors: | Chao-Min Liu Yin-Long Guo Qi-Hai Xu Yong-Min Liamg Yong-Xiang Ma |
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| Institution: | 1. National Laboratory Of Applied Organic Chemistry, Lanzhou University , Lanzhou, 730000, P. R. China;2. Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences , 354 Fenglin Road, Shanghai, 200032, P. R. China |
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| Abstract: | A convenient synthesis of C5H5Fe(1,2-C5H3(CH2R)(Heteroaryl)], (R=NMe2, Heteroaryl=5-benzoylthien-2-yl(3a), 2-nitropyrid-5-yl(3b), 5-nitrothien-2-yl(3c), 6-methoxy-8-nitroquino-3-yl(3d); R=MeO, Heteroaryl=5-benzoylthien-2-yl(6a), 2-nitropyrid-5-yl)(6b) from C5H5Fe(1,2-C5H3(CH2R)(SnBu3)], (R=NMe2, OMe), via Stille coupling reaction is described. |
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