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Convenient Synthesis of Aryl Ferrocenyl Ketone via Palladium‐Catalyzed Carbonylation Coupling
Authors:Dong Yang  Zenglu Liu  Ying Li
Affiliation:1. State Key Laboratory of Applied Organic Chemistry , Lanzhou University , Lanzhou, China;2. Pharmacy College of Shanghai Jiao Tong University , Shanghai, China
Abstract:A series of aryl ferrocenyl ketones were prepared from iodoferrocene, phenylboronic acids, and CO via palladium‐catalyzed carbonylation coupling in a short time. The procedure was efficient and convenient and avoided formation of diacylated derivatives compared with currently available Friedel–Crafts acylation methodologies.
Keywords:aryl ferrocenyl ketone  carbonylation  coupling  iodoferrocene  palladium catalysis
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