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Dimethyl Sulfoxide Pivaloyl Chloride: A New Reagent for Oxidation of Alcohols to Carbonyls
Authors:Abhishek Dubey  Subba Rao V. Kandula
Affiliation:Division of Organic Chemistry , National Chemical Laboratory , Pune, India
Abstract:An efficient procedure for conversion of alcohols to the corresponding carbonyl compounds, an alternative to the classical Swern oxidation, is described. Pivaloyl chloride is employed as a mild and inexpensive electrophile. A possible reaction mechanism is proposed.
Keywords:alcohols  carbonyls  DMSO  pivaloyl chloride  Swern oxidation
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