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Efficient Role of Ionic Liquid (bmim)HSO4 as Novel Catalyst for Monotetrahydropyranylation of Diols and Tetrahydropyranylation of Alcohols
Authors:Jasvinder Singh  Neeraj Gupta  Goverdhan L Kad  Jasamrit Kaur
Institution:1. Department of Chemistry and Centre for Advanced Studies in Chemistry , Panjab University , Chandigarh, India jsbrar_pu@yahoo.com;3. Department of Chemistry and Centre for Advanced Studies in Chemistry , Panjab University , Chandigarh, India;4. GGDSD College , Chandigarh, India
Abstract:A simple procedure for the monotetrahydropyranylation of diols and alcohols, in excellent to moderate yields, has been reported using a catalytic amount of the acidic ionic liquid, 1‐butyl‐3‐methylimidazolium hydrogensulphate (bmim)HSO4 under microwave and ultrasonic irradiation. Results have been compared with those obtained by reactions in the absence of these energies, and effectiveness of the recycled ionic liquid has also been studied.
Keywords:Ionic liquid  microwave irradiation  monotetrahydropyranylation  selective  solvent‐free  tetrahydropyranylation  ultrasound
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