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Facile Synthesis of Bibenzyl by Reductive Homocoupling of Benzyl Halides in Aqueous Media
Authors:Jian Liu  Bin Li
Affiliation:1. Department of Chemistry , Beijing Normal University , Beijing, China liujianbnu@sina.com;3. Department of Chemistry , Beijing Normal University , Beijing, China
Abstract:A facile synthesis of bibenzyl derivatives by reductive homocoupling reaction is described. Treatment of benzyl halides with metallic iron powder in the presence of a catalytic amount of cuprous salt in aqueous media gives bibenzyls in good yields.
Keywords:aqueous media  bibenzyl  iron powder  reductive homocoupling reaction
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