On Attempted Oxidative Cyclisation of Isomeric N,N'-Diphenylphenylenediamines and Their N,N'-Dimethyl Derivatives by Palladium(II) Acetate and Uv Light |
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Authors: | Manas Chakrabarty Archana Batabyal Shampa Khasnobis |
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Institution: | 1. Dept. of Chemistry , Bose Institute , 93/1, A.P.C. Road, Calcutta, 700009, India;2. Dept. of Chemistry , St. Paul's College , Calcutta, 700009;3. Dept. of Chemistry , A.J.C. Bose College , Calcutta, 700020, India |
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Abstract: | The cyclisation of N,N'-diphenyl-o-, m- and p-phenylenediamines and their N,N'-dimethyl derivatives by palladium(II) acetate and UV light separately led to both bis-cyclisation, furnishing indolocarbazoles, and mono-cyclisations with cleavage as well as retention of one substituent, producing substituted carbazoles. |
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