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Solvent-Free Esterification of Carboxylic Acids and Alcohols in the Presence of Silphos [PCl3-n(SiO2)n] as a Heterogeneous Phosphine Reagent
Authors:Ambati Narasimha Rao  Kumaran Ganesan  Chandra Kant Shinde
Affiliation:1. Defence Research and Development Establishment , Gwalior , India rao.ambati@rediffmail.com;3. Defence Research and Development Establishment , Gwalior , India;4. Jiwaji University , Gwalior , India
Abstract:An efficient solvent-free method for the preparation of esters from various aromatic and aliphatic acids with primary, secondary, and tertiary alcohols using a heterogeneous phosphine reagent, silphos [PCl3-n(SiO2)n], in good yields is reported.
Keywords:Alcohols  carboxylic acids  esterification  heterogeneous  silphos
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